Expo Organics

L-Carvone vs D-Carvone — Spearmint vs Caraway Isomer Bulk Buyer Guide | Expo Organics

BULK F&F BUYER GUIDE

L-Carvone vs D-Carvone — Mirror-Image Isomers, Two Different Industries

Same molecule. Same chemical formula. Two opposite mirror-image structures (chirality) — and two completely different organoleptic profiles, FCC / FEMA roles, and downstream industries. Here’s the spec-sheet comparison for B2B flavour, F&F, oral-care and pharma buyers, supplied direct from our Delhi-NCR aromatic-chemicals plant.

L-Carvone (Levo)

Spearmint / pharma chirality · (S)-(+)-Carvone

  • Spearmint-note organoleptic profile — cool, sweet, herbal
  • Optical rotation: levorotatory (−60° to −62°)
  • FEMA 2249 · FCC compliant · oral-care & gum approved
  • Primary use: spearmint flavour, toothpaste, mouthwash, gum
  • Pharma chiral building-block for synthesis routes
  • Substitutes / extends natural spearmint oil
vs

D-Carvone (Dextro)

Caraway / dill chirality · (R)-(−)-Carvone

  • Caraway / dill organoleptic profile — warm, spicy, bread-y
  • Optical rotation: dextrorotatory (+60° to +62°)
  • FEMA 2250 · FCC compliant · bakery / food-flavour approved
  • Primary use: caraway flavour, bakery, savoury, dill flavour
  • Bio-based sprout-suppressant for potato storage
  • Substitutes / extends natural caraway & dill oil

Side-by-side spec comparison

Parameter L-Carvone (Levo) D-Carvone (Dextro)
IUPAC name (S)-(+)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one (R)-(−)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one
CAS 6485-40-1 2244-16-8
FEMA 2249 2250
Chirality S (levo, −) R (dextro, +)
Organoleptic Spearmint, cool, sweet, herbal Caraway / dill, warm, spicy, bread-y
Specific gravity (20°C) 0.957–0.961 0.957–0.961
Refractive index (20°C) 1.4970–1.5000 1.4970–1.5000
Optical rotation −60° to −62° +60° to +62°
Assay (GC) ≥98% ≥98%
Primary industry Oral care, gum, pharma chiral Bakery, savoury flavour, potato sprout suppression
Common pack 25 kg HDPE drum 25 kg HDPE drum
Pricing tier Premium (oral-care grade) Standard food-flavour grade

When to choose L-Carvone (Levo)

Toothpaste & mouthwash

Spearmint-note formulations rely on L-Carvone as the primary cooling-flavour molecule alongside menthol.

Chewing gum

Spearmint and “fresh-mint” gum recipes are built around L-Carvone — long-lasting note in the bolus.

Pharma chiral synthesis

Single-enantiomer building-block for pharma intermediates and active-ingredient synthesis.

Spearmint oil extension

Used to extend / blend with natural spearmint oil for cost-optimised flavour bases.

When to choose D-Carvone (Dextro)

Caraway-flavoured bakery

Rye breads, pretzels, sausage seasonings, kümmel cordials.

Dill flavour formulations

Pickle seasonings, dill-flavoured snacks, savoury sauce bases.

Potato sprout suppression

Bio-based alternative to chlorpropham in long-term potato storage — D-Carvone vapour treatment.

Caraway oil extension

Cost-optimised flavour extension of natural caraway / dill oil.

What’s common between L- and D-Carvone from our plant

Both isomers ship from the same Delhi-NCR aromatic-chemicals facility with the same QC architecture:

  • ≥98% GC assay per lot · GC-MS chromatogram attached to COA
  • NABL third-party testing on retain-sample reference
  • Optical rotation measured per lot to verify chirality (critical for both grades)
  • FEMA + FCC documentation; allergen statement; country-of-origin certificate
  • REACH / EFSA / FDA awareness — paperwork pack on request
  • 25 kg HDPE / 200 kg MS drum packaging; FCL for repeat buyers
  • Sample programme: paid, 100% credit-back against bulk order in 60 days

Buyer FAQ — most asked questions on this pair

Q: Can I substitute L for D, or vice-versa?
No — they smell and taste completely different despite the identical molecular formula. The chirality flip is the entire reason these molecules exist as two separate FEMA numbers.

Q: Why does optical rotation matter to my QC team?
Optical rotation is the only physical parameter that reliably distinguishes L from D in routine QC. Most other parameters (RI, SG, assay) are identical. We measure per lot and attach the reading to every COA.

Q: Are these synthetic or natural?
Both grades are typically synthesised from limonene oxidation chemistry. Natural-equivalent grades (ex-spearmint or ex-caraway oil) are available on prior confirmation — different pricing tier.

Q: Minimum order?
25 kg HDPE drum entry. Drum and FCL pricing tiers on /pricing-tiers/.

Q: Are you the manufacturer or a trader?
Manufacturer-direct. The supplier-to-suppliers brands (you may have heard of) source from facilities like ours. Skip the middlemen.

Get bulk pricing on L-Carvone (Levo) or D-Carvone (Dextro)

One RFQ — both quotes back the same working day. Sample plan with full credit-back if you want to qualify first.

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